The authors describe the behavioral interactions of piscivorous mid-water and demersal fishes at subtropical live-bottom reefs off the coast of Georgia and off the west coast of Florida in the northeast Gulf of Mexico. The observations are used to construct a topological behavior web of the interactions of mid-water and demersal piscivores, their prey, and those associated species that modify predator-prey interactions. Results show that inter-specific behavioral interactions are common attributes of piscivores in these reef fish communities. The authors propose a framework for assessing the demographic consequences of such interactions. Data for this study were collected using a modified Roving Diver Technique, the method employed by REEF surveyors. One of the co-authors, Dave Grenda, is a member of REEF's Advanced Assessment Team.